Saddle-Splayed Layers of the B4 Phase

Like bananas in a bunch, bent-core molecules tend to pack together in layers but have difficulty forming spatial arrangements that are uniform. The most exotic example of this is the B4 phase, the structure of which was recently deciphered by Center researchers and collaborators. This atomic force microscopy image shows the contortions of the layering in this phase, which fills space with layers having a saddle-like deformation, a consequence of intra-layer packing frustration.

Saddle-Splayed Layers of the B4 Phase
 

 

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